[1]林灵燕,范宝殿.CuGaO2空穴传输层的钙钛矿太阳电池的数值模拟[J].泉州师范学院学报,2018,(02):50-54.
 LIN Lingyan,FAN Baodian.The Numerical Simulation of CuGaO2 Hole Transport Layer Perovskite Solar Cells[J].,2018,(02):50-54.
点击复制

CuGaO2空穴传输层的钙钛矿太阳电池的数值模拟()
分享到:

《泉州师范学院学报》[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2018年02期
页码:
50-54
栏目:
数理科学
出版日期:
2018-04-15

文章信息/Info

Title:
The Numerical Simulation of CuGaO2 Hole Transport Layer Perovskite Solar Cells
文章编号:
1009-8224(2018)02-0050-05
作者:
林灵燕12范宝殿12
1.福建江夏学院 电子信息科学学院,福建 福州 350108; 2.福建江夏学院 先进光伏技术研究所,福建 福州 350108
Author(s):
LIN Lingyan12FAN Baodian12
1.College of Electronic Information Science,Fujian Jiangxia University,Fujian 350108,China; 2.Institute of Advanced Photovoltaics,Fujian Jiangxia University,Fujian 350108,China
关键词:
钙钛矿电池 模拟 CuGaO2
Keywords:
perovskite solar cell simulation CuGaO2
分类号:
O0475
文献标志码:
A
摘要:
采用 SCAPS-1D 电池模拟软件,对以CuGaO2作为空穴传输层的平面异质结钙钛矿太阳电池进行数值模拟,模拟的电池结构为FTO/TiO2/CH3NH3PbI3 /CuGaO2/Au.分析了钙钛矿吸收层厚度、缺陷态浓度、CH3NH3PbI3/CuGaO2 和TiO2/CH3NH3PbI3界面缺陷浓度对电池光电性能的影响,并且通过模拟优化得到CuGaO2 为空穴传输层的钙钛矿电池的最佳I-U特性为:Uoc=1.14 V,Jsc=23.84 mA/cm2,FF=85.95%,PCE=23.42%.
Abstract:
The solar cell simulation software SCAPS-1D was used to simulate the planar heterojunction perovskite solar cellwith CuGaO2 as hole-transporting layer.The simulated cell structure was FTO/TiO2/CH3NH3PbI3/CuGaO2/Au.In this paper,thethickness of the perovskite absorber layer, defect density,the concentration of CH3NH3PbI3/CuGaO2 and TiO2/CH3NH3PbI3interfacial defects on the photoelectric properties of solar cell were mainly analyzed.The optimum I-U characteristics ofthe perovskite solar cell with CuGaO2 as hole-transporting layer was simulated and optimized as follows:Uoc=1.14 V,Jsc =23.84 mA/cm2,FF=85.95% and PCE=23.42%.

参考文献/References:

[1] KOJIMA A,TESHIMA K,SHIRAI Y,et al.Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J].Journal of the American Chemical Society,2009,131(17):6050-6051.
[2] SALIBA M,MATSUI T,DOMANSKI K,et al.Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance[J].Science,2016,354(6309):206-209.
[3] WEHRENFENNIG C,EPERON G E,JOHNSTON M B,et al.High charge carrier mobilities and lifetimes in organolead trihalideperovskites[J].Advanced Materials,2014,26(10):1584-1589.
[4] BAIKIE T,FANG Y,KADRO J M,et al.Synthesis and crystal chemistry of the hybrid perovskite(CH3NH3)PbI3 for solid-statesensitised solar cell applications[J].Journal of Materials Chemistry A,2013,1:5628-5641.
[5] YANG W S,NOH J H,JEON N J,et al.High-performance photovoltaic perovskite layers fabricated through intramolecularexchange[J].Science,2015,348(6240):1234-1237.
[6] DOCAMPO P,HEY A,GULDIN S,et al.Pore filling of spiro-OMeTAD in solid-state dye-sensitized solar cells determined viaoptical reflectometry[J].Advanced Functional Materials,2012,22:5010-5019.
[7] ADÈLE R,BENOIT C,LOÏC L P,et al.CuGaO2: a promising alternative for NiO in p-type dye solar cells[J].Journal ofMaterials Chemistry,2012,22:14353-14356.
[8] ZHANG H,WANG H,CHEN W,et al.CuGaO2:a promising inorganic hole-transporting material for highly efficient and stableperovskite solar cells[J].Advanced Materials,2017,29(8):1604984.
[9] LEE M M,TEUSCHER J,MIYASAKA T,et al.Efficient hybrid solar cells based on meso-superstructured organometal halideperovskites[J].Science,2012,338(6):643-647.
[10] HOMES C C,VOGT T,SHAPIRO S M,et al.Optical response of high-dielectric-constant perovskite-related oxide[J].Science,2001,293(5530):673-676.
[11] HIRASAWA M,ISHIHARA T,GOTO T,et al.Magnetoabsorption of the lowest exciton in perovskite-type compound(CH3NH3)PbI3 [J].Physics B:Condensed Matter,1994,201:427-430.
[12] NOH J H,IM S H,HEO J H,et al.Chemical management for colorful,efficient,and stable inorganic-organic hybridnanostructured solar cells[J].Nano Letters,2013,13(4):1764-1769.

备注/Memo

备注/Memo:
收稿日期:2018-02-03
作者简介:林灵燕(1989-),女,福建莆田人,硕士,讲师,主要从事微电子材料与器件研究.
基金项目:福建省中青年教师教育科研项目(JAT170622,JAT170630)
更新日期/Last Update: 2018-04-15