[1]洪超,林建清*,曾小楎,等.纳米催化电解法处理磺胺二甲基嘧啶废水[J].泉州师范学院学报,2019,(02):6-11.
 HONG Chao,LIN Jianqing*,ZENG Xiaohui,et al.A Study on the Treatment of Sulfamethazine Wastewater by Nano Catalytic Electrolysis[J].,2019,(02):6-11.
点击复制

纳米催化电解法处理磺胺二甲基嘧啶废水()
分享到:

《泉州师范学院学报》[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2019年02期
页码:
6-11
栏目:
化学·生命科学
出版日期:
2019-04-15

文章信息/Info

Title:
A Study on the Treatment of Sulfamethazine Wastewater by Nano Catalytic Electrolysis
文章编号:
1009-8224(2019)02-0006-06
作者:
洪超1林建清12*曾小楎1高春柏1巫晶晶12黄宁12林锦美12黄全佳3许杰龙3
1.集美大学 食品与生物工程学院,福建 厦门 361021; 2.集美大学 环境工程研究所,福建 厦门 361021; 3.厦门市环境科学研究院,福建 厦门 361006
Author(s):
HONG Chao1LIN Jianqing12*ZENG Xiaohui1GAO Chunbo1WU Jingjing12HUANG Ning12LIN Jinmei12HUANG Quanjia3XU Jielong3
1.College of Food and Biological Engineering,Jimei University,Fujian 361021,China; 2.Institute of Environmental Engineering,Jimei University,Fujian 361021,China; 3.Xiamen Institute of Environmental Science,Fujian 361006,China
关键词:
纳米催化电解 磺胺二甲基嘧啶 CODMn 固相萃取-高效液相色谱
Keywords:
nano-catalytic electrolysis sulfamethazine CODMn solid phase extraction-high performance liquid chromatography(SPE-HPLC)
分类号:
X787
文献标志码:
A
摘要:
为了解决磺胺类抗生素废水处理的难题,利用新型纳米催化电解技术处理并探讨其最佳处理条件及效果.以模拟磺胺二甲基嘧啶废水为研究对象,采用新型纳米催化电解技术处理,讨论电解时间、电压、pH、电解质浓度对磺胺二甲基嘧啶废水的处理效果.得出废水处理的最佳技术条件为:废水pH为13、电解电压为6 V、NaCl电解质浓度为1.5%.在此条件下,CODMn的去除率为86.98%,磺胺二甲基嘧啶的去除率为90.21%.该工艺对磺胺二甲基嘧啶废水的处理效果较好.
Abstract:
In order to solve the problem of sulfa antibiotic wastewater treatment,the new nano-catalytic electrolysis technology was used to treat and discuss its optimal treatment conditions and effects.Taking the typical sulfa antibiotic sulfamethazine wastewater as the research object,the new nano-catalytic electrolysis technology was used to discuss the effect of electrolysis time,voltage,pH and electrolyte concentration on the treatment effect of sulfamethazine wastewater.The best technical conditions for wastewater treatment are:pH value of wastewater of 13,electrolysis voltage of 6 V,and NaCl electrolyte concentration of 1.5%.Under this condition,the removal rate of CODMn was 86.98%,and the removal rate of sulfamethazine was 90.21%.The process has a good effect on the treatment of sulfamethazine wastewater.

参考文献/References:

[1] 赵涛,丘锦荣,蒋成爱,等.水环境中磺胺类抗生素的污染现状与处理技术研究进展[J].环境污染与防治,2017,39(10):1147-1152.
[2] SKOLD,OLA.Sulfonamide resistance:mechanisms and trends[J].Drug Resistance Updates Reviews & Commentaries in Antimicrobial & Anticancer Chemotherapy,2000,3(3):155-160.
[3] SCOZZAFAVA A,OWA T,MASTROLORENZO A,et al.Anticancer and antiviral sulfonamides.[J].Current Medicinal Chemistry,2003,10(11):925-953.
[4] GOBEL A,MCARDELL C,JOSS A,et al.Fate of sulfonamides,macrolides,and trimethoprim in different wastewater treatment technologies[J].Science of the Total Environment,2007,372(2/3):361-371.
[5] GARCIA GALAN M J,SILIV DIAZ-CRUZ M,BARCELO D.Identification and determination of metabolites and degradation products of sulfonamide antibiotics[J].Trends in Analytical Chemistry,2008,27(11):1008-1022.
[6] CHANG H,HU J Y,WANG L Z,et al.Occurrence of sulfonamide antibiotics in sewage treatment plants[J].Chinese Science Bulletin,2008,53(4):514-520.
[7] 康蓓蓓,黎春燕.废水中磺胺类抗生素的控制技术研究现状[J].科技资讯,2017,15(29):117-118.
[8] BEN W,QIANG Z,PAN X,et al.Removal of veterinary antibiotics from sequencing batch reactor(SBR)pretreated swine wastewater by Fenton's reagent[J].Water Research,2009,43(17):4392-402.
[9] 张猛.电极-SBR法对四环素类抗生素的去除及抗性基因的影响[D].北京:北京化工大学,2017.
[10] GARCIA GALAN M J,DIAZ-CRUZ M S,BARCELO D.Removal of sulfonamide antibiotics upon conventional activated sludge and advanced membrane bioreactor treatment[J].Analytical and Bioanalytical Chemistry,2012,404(5):1505-1515.
[11] YANG S,LIN C,WU C,et al.Fate of sulfonamide antibiotics in contact with activated sludge-sorption and biodegradation[J].Water Research,2012,46(4):1301-1308.
[12] FENG Y J,LI X Y.Electro-catalytic oxidation of phenol on several metal-oxide electrodes in aqueous solution[J].Water Research,2003,37(10):2399-2407.
[13] 陈立义,李丹,杨幼军,等.纳米催化电解[NCE]在污水处理领域中的应用[C]//全国城镇污水处理厂提标改造技术交流研讨会论文集:2012.
[14] 王志刚.电化学法对养殖废水中污染物去除研究[D].重庆:西南大学,2013:45.
[15] 钟登杰,胡芝悦.电化学法处理生活污水研究进展[J].工业水处理,2016,36(4):5-9.
[16] 李军.磺胺类和四环素类抗生素不同解离形态与ROS的光氧化反应动力学及转化途径[D].上海:上海海洋大学,2016.
[17] 吴星.Fe-C/Fenton+IC+A/O处理抗生素制药废水的研究与应用[D].南昌:南昌大学,2016.
[18] PANIZZA M,BOCCA C,CERISOLA G.Electrochemical treatment of wastewater containing polyaromatic organic pollutants[J].Water Research,2000,34(9):2601-2605.
[19] GARCIAGALAN M J,DIAZCRUZ M S,BARCELO D.Occurrence of sulfonamide residues along the Ebro River basin:removal in wastewater treatment plants and environmental impact assessment[J].Environment International,2011,37(2):462-473.
[20] MEZYK S P,NEUBAUER T J,COOPER W J,et al.Free-radical-induced oxidative and reductive degradation of sulfa drugs in water:absolute kinetics and efficiencies of hydroxyl radical and hydrated electron reactions[J].The Journal of Physical Chemistry A,2007,111(37):9019-9024.
[21] 常红,胡建英,王乐征,等.城市污水处理厂中磺胺类抗生素的调查研究[J].科学通报,2008(2):159-164.
[22] SUAREZ S,LEMA J M,OMIL F.Pre-treatment of hospital wastewater by coagulation-flocculation and flotation[J].Bioresource Technology,2009,100(7):2138-2146.
[23] 荆国华,周作明.UV/Fenton处理三唑磷农药废水[J].华侨大学学报(自然科学版),2006,27(2):197-200.
[24] ZHANG C,LAI C,ZENG G,et al.Efficacy of carbonaceous nanocomposites for sorbing ionizable antibiotic sulfamethazine from aqueous solution[J].Water Research,2016,95:103-112.
[25] 牛瑞华.人工湿地对磺胺类抗生素的去除效果及影响因素研究[D].上海:东华大学,2014.
[26] 郑芳芳.树脂吸附去除水中抗生素的行为与机理[D].南京:南京师范大学,2012.
[27] CHEN Z,CUI L,ZENG G,et al.Efficacy of carbonaceous nanocomposites for sorbing ionizable antibiotic sulfamethazine from aqueous solution[J].Water Research,2016,95:103-112.

备注/Memo

备注/Memo:
收稿日期:2018-11-01
通信作者:林建清(1966—),男,福建福州人,副教授,博士,从事水环境污染与控制技术研究,E-mail:jqlin@jmu.edu.cn.
基金项目:福建省社会发展引导性项目(2015Y0072); 福建省环保科技计划项目(2013R006); 福建省自然科学基金资助项目(2015J01168); 福建省中青年教师教育科研项目(JAT170307)
更新日期/Last Update: 2019-04-15