[1]郑燕玉,卓东贤,顾芙蓉.甲基苯基硅改性腰果酚醛树脂涂料的制备及性能[J].泉州师范学院学报,2020,(06):1-5.
　ZHENG Yanyu,ZHUO Dongxian,GU Furong.The Preparation and Properties of Methyl Phenyl Silicone/Cardanol-Aldehyde Resin Composite Coating[J].,2020,(06):1-5.
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甲基苯基硅改性腰果酚醛树脂涂料的制备及性能()
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《泉州师范学院学报》[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2020年06期
页码:
1-5
栏目:
化学与生命科学
出版日期:
2020-12-15

文章信息/Info

Title:
The Preparation and Properties of Methyl Phenyl Silicone/Cardanol-Aldehyde Resin Composite Coating
文章编号:
1009-8224(2020)06-0001-05
作者:
郑燕玉; 卓东贤; 顾芙蓉
泉州师范学院 化工与材料学院,福建 泉州 362000
Author(s):
ZHENG Yanyu; ZHUO Dongxian; GU Furong
School of Chemical Engineering and Materials,Quanzhou Normal University,Quanzhou Fujian 362000,China
关键词:
甲基苯基硅;  腰果酚醛树脂;  复合涂料;  涂料
Keywords:
methyl phenyl silicone;  cardanol-aldehyderesin;  composite material;  coating
分类号:
F590.8
文献标志码:
A
摘要:
以苯基三氯硅烷(PTS)、二苯基二氯硅烷(DPS)和二甲基二氯硅烷(DMS)为原料,通过水解法合成甲基苯基硅树脂(PMPS),将其与腰果酚甲醛缩聚物共混制备甲基苯基硅/腰果酚醛树脂复合涂料(PMPS/PCF).用IR、UV表征PMPS/PCF的结构,并研究该复合涂料的耐热性能、抗紫外性能、耐腐蚀性及物理机械性能.结果表明:有机硅上的硅羟基与PCF的酚羟基聚合形成硅氧键,使复合涂料的热稳定性提高; 当PMPS为PMPS/PCF含量的20%时,复合涂料的硬度由HB提高到6H,耐冲击性从20 kg·cm提高到35 kg·cm,光泽度由95.2%升高到100.4%.
Abstract:
Methyl phenyl silicone polymer(PMPS)was synthesized by hydrolysis,with dichlorodimethysilane(DMS), diphenyldichlorosilane(DPS)and phenyltrichlorosilane(PTS)as rawmaterial. PMPS/PCF composite coating was prepared via PMPS blended with cardanol-aldehyde formaldehyde condensate(PCF). The structure of PMPS/PCF was examined by IR and UV.Thethermal stability of PMPS/PCF composite coating, anti-uv functioning, mechanical property, anticorrosive properties were investigated. IR and UV spectra indicated that PMPSwas condensed with PCF into crosslinking structure. The thermal stability of PMPS/PCF was better than PCF.When PMPS/PCF contained 20% of PMPS, the performance was the best,thehardness increased from HB to 6H; the inpact resistance increased from 20 kg·cm to 35 kg·cm; the glossiness increased from 95.2% to 100.4%.

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相似文献/References:

[1]郑燕玉,刘小英,潘亦真.SiO2/有机硅/腰果酚醛树脂复合涂料的制备与性能[J].泉州师范学院学报,2019,(02):1.
　ZHENG Yanyu,LIU Xiaoying,PAN Yizhen.Synthesis and Properties of SiO2/ Silicone/Cardanol-Aldehyde Resin Composite Coating[J].,2019,(06):1.

备注/Memo

备注/Memo:
收稿日期:2020-05-16
作者简介:郑燕玉(1966-),女,福建永春人,教授,博士,从事天然高分子研究.
基金项目:福建省教育厅项目(JK2014038); 福建省科技厅项目(2015H0047); 泉州市港湾计划人才团队(2018CT003); 福建省高校科技创新团队(IRTSTFJ)
更新日期/Last Update: 2020-12-15